Details
Using CCB-PIO-DB15-O5ST allows to have one Input and one Output:

But using the DM-USBIO-00 doesn’t allows to have Common Input contrary to what is stated in the DM-USBIO-00 wiring diagram:

CCB-PIO-DB15-05ST is a feature reduced IO cable.
It has just 1 output and 1 input.
The input is referring to GND pin 4.
There is no input common on this cable, therefore pin 13 is unconnected.
So, Pin 13 on DM-USBIO-00 is not connected too.